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A molecule made from two rubidium atoms can have a permanent electric dipole when the atoms occupy different electronic states. In the unusual ultracold Rydberg molecule reported in 2011, one atom is excited to a high-lying state and the other remains in its ground state. Their interaction distorts the Rydberg electron’s distribution, producing a body-fixed dipole of about 1 Debye. This refines the familiar symmetry rule; it does not make ordinary molecules of identical atoms polar.
Why identical atoms are usually expected to have no permanent dipole
A permanent electric dipole requires an uneven distribution of positive and negative charge. In the standard picture of a homonuclear diatomic molecule—one made from two atoms of the same element—the two ends are equivalent. Inversion symmetry therefore rules out a permanent dipole along the molecular axis.
That argument concerns the molecule’s symmetry, not just the names of its atoms. Two rubidium nuclei can be identical while the molecule’s prepared electronic state treats their surroundings differently. The 2011 result is an exceptional example of that distinction, not a general exception for all homonuclear molecules.
What made the rubidium Rydberg molecule different
The molecule was an ultralong-range Rydberg dimer: one rubidium atom was in its ground state, while the other had an electron excited to a high-lying Rydberg state. The ground-state atom sat within the spatial extent of the Rydberg electron’s wavefunction. In earlier work, scattering between that electron and the ground-state atom was shown to provide an attractive interaction that can bind the pair. Bendkowsky et al., Nature (2009)
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In the 2011 system, the interaction with the nearby ground-state atom mixed a nearly degenerate electronic manifold into the Rydberg state. That admixture shifted electron density toward the perturbing atom. The resulting electronic distribution was asymmetric even though both nuclei were rubidium. The observed linear Stark response—the molecule’s response to an applied electric field—provided evidence for a permanent dipole. Spectroscopy and detailed calculations supported the result. Li et al., Science (2011)
What the reported dipole means
Li and colleagues reported a dipole moment on the order of 1 Debye for this homonuclear Rydberg molecule. The figure describes the permanent dipole associated with the molecule-fixed electronic state; it does not mean the molecule necessarily points in one fixed direction in the laboratory when no field is applied. The experiment’s Stark response is how the dipole’s presence was identified. The 2011 paper
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How this differs from a trilobite Rydberg molecule
“Trilobite” refers to a distinct kind of Rydberg molecular state, involving high-angular-momentum electronic character. A 2023 peer-reviewed report describes pure trilobite rubidium Rydberg molecules with dipoles in the kilo-Debye range and two vibrational series. Those much larger values belong to a different state regime; they are not revised measurements of the approximately 1-Debye molecule reported in 2011. Exploring the vibrational series of pure trilobite Rydberg molecules (2023)
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1Repair Windows errors before they cause bigger problems2Fix the driver behind crashes, sound loss and screen glitches3Clear out junk files and repair common Windows errors| Feature | 2011 homonuclear Rydberg molecule | 2023 pure trilobite Rydberg molecules |
|---|---|---|
| Electronic character | Low-angular-momentum Rydberg state with an admixture of a nearly degenerate manifold, as described by Li et al. (2011) Source | Pure trilobite states with high-angular-momentum character, as described in the 2023 study Source |
| Reported dipole scale | On the order of 1 Debye Source | Kilo-Debye range Source |
| Experimental context | Spectroscopy and a linear Stark response were used to identify the dipole; detailed calculations agreed with the observations Source | The study reports two vibrational series; the cited summary does not state a directly comparable Stark-measurement detail Source |
So, can a homonuclear molecule have a permanent dipole?
Yes, in a specially prepared electronic state such as this ultracold rubidium Rydberg molecule. The key is that identical nuclei do not force every possible electronic state to distribute charge symmetrically. Here, asymmetric excitation and the interaction with the second atom distort the electron density, creating a permanent body-fixed dipole without changing the atoms’ identity.
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